Mixed matrix membranes for process intensification in electrodialysis of amino acids
Readi, O. M. K.
2014
Source PublicationJournal of Chemical Technology and Biotechnology
ISSN0268-2575
Volume89Issue:3Pages:425-435
AbstractBACKGROUNDAmino acids are valuable intermediates in the biobased economy for the production of chemicals. Electro-membrane processes combined with enzymatic modification have been investigated as an alternative technology for the fractionation of a mixture of amino acids with almost identical charge behavior. Up to now, the modification and subsequent separation were performed in two separate reactors. An interesting approach is the integration of both unit operations into one single device using mixed matrix membranes (MMMs) as platform for enzymatic conversion. RESULTSMMMs containing the enzyme glutamic acid decarboxylase (GAD, EC 4.1.1.15) Relizyme EP403/S as carrier were prepared showing satisfactory mechanical stability and enzymatic activity for L-glutamic acid conversion into -aminobutyric acid (GABA). ED with integrated MMM for simultaneous enzymatic decarboxylation of L-glutamic acid to GABA (33% conversion) and further separation of L-aspartic acid and unconverted L-glutamic acid from GABA was successful leading to current efficiency of 40% and low energy consumption of 3 kWh kg(-1). CONCLUSIONSTogether with the high mechanical stability obtained for the MMMs, this opens the route towards process intensification, combining enzymatic conversion and separation with electrodialysis in one integrated process for the successful isolation of amino acids for biorefinery applications. (c) 2013 Society of Chemical Industry
Document Type期刊论文
Identifierhttps://ir.xtbg.ac.cn/handle/353005/7335
Collection热带植物资源可持续利用重点实验室特色文献_小桐子相关文献
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GB/T 7714
Readi, O. M. K.. Mixed matrix membranes for process intensification in electrodialysis of amino acids[J]. Journal of Chemical Technology and Biotechnology,2014,89(3):425-435.
APA Readi, O. M. K..(2014).Mixed matrix membranes for process intensification in electrodialysis of amino acids.Journal of Chemical Technology and Biotechnology,89(3),425-435.
MLA Readi, O. M. K.."Mixed matrix membranes for process intensification in electrodialysis of amino acids".Journal of Chemical Technology and Biotechnology 89.3(2014):425-435.
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