Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst
Ayodele, O. O.
2014
Source PublicationBiomass & Bioenergy
ISSN0961-9534
Volume70Pages:239-248
AbstractCalophyllum inophyllum oil is non-edible with high potential as biodiesel feedstock. This study addressed the multiple stages involved in producing biodiesel from C. inophyllum oil by synthesizing a solid acid catalyst from freely available biomass. Microcrystalline cellulose used as the starting material was pyrolyzed to obtain a polycyclic aromatic carbon capable of binding SO3H groups upon sulfonation in concentrated sulfuric acid. Esterification activity of the catalyst towards the free fatty acid found in C. inophyllum oil was superior to the catalyst obtained from D-glucose. The catalyst was also capable of one-pot production of biodiesel from the feedstock with acid value of 29.5 mg KOH/g. High conversion to fatty acid methyl esters (similar to 99 wt.%) was achieved using 1:15 M ratio of oil to methanol with a catalyst loading of 5 wt.% at 180 degrees C for 4 h. The catalyst also displayed high catalytic stability by retaining about 85% of its original activity. This work shows that the catalyst can replace homogeneous catalysts currently employed to produce biodiesel from C. inophyllum oil. (C) 2014 Elsevier Ltd. All rights reserved.
Document Type期刊论文
Identifierhttps://ir.xtbg.ac.cn/handle/353005/7189
Collection热带植物资源可持续利用重点实验室特色文献_小桐子相关文献
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GB/T 7714
Ayodele, O. O.. Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst[J]. Biomass & Bioenergy,2014,70:239-248.
APA Ayodele, O. O..(2014).Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst.Biomass & Bioenergy,70,239-248.
MLA Ayodele, O. O.."Production of biodiesel from Calophyllum inophyllum oil using a cellulose-derived catalyst".Biomass & Bioenergy 70(2014):239-248.
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